ok, now that I am in front of a DB, here is the final query for you (thanks to Steven Klassen for the assist with the join)
SELECT Nodes.NodeCaption AS 'Node', ConfigArchive.ConfigTitle AS 'Config'
FROM [ConfigMgmt].[dbo].[Nodes]
JOIN [ConfigMgmt].[dbo].[ConfigArchive] ON '{' + CAST (Nodes.NodeID AS VarChar (100)) + '}' = ConfigArchive.NodeID
ORDER BY Nodes.NodeCaption
Replacing [ConfigMgmt] with whatever you have named your NCM database.
This new format will give you results like the attached:
